Add 3/4 cup heavy cream and espresso powder to a saucepan over medium heat. Whisk until espresso has dissolved and heat until hot, but don't simmer. About 1 minute.
In a bowl, add the egg yolks, sugar, and salt and whisk to combine. Slowly pour in the hot cream and whisk. Transfer the mixture back to the sauce and continue to cook over low heat. Stir constantly, until the liquid coats the back of a spoon, about 3-4 minutes.
Remove pan from heat. Add the chopped chocolate and vanilla and whisk till smooth. Let cool to room temp, stirring occasionally, about 40 minutes.
In a medium bowl, add 1 1/4 cups heavy cream and beat with a hand mixer on medium speed until stiff peaks form, about 4 minutes. Pour chocolate mixture over the whipped cream and fold, using a spatuls, until just combined. Carefully pour the chocolate mousse into the pie crust and transfer to the refrigerator to chill for six hours or overnight.